![]() Blair MacPhail, M.D.īlair MacPhail, M.D., joined the Community Howard Regional Health medical staff as an interventional cardiologist in 2013. Kumar is board certified in vascular surgery. He completed a vascular surgery fellowship at Northwestern Memorial Hospital in Chicago.ĭr. He attended medical school at the University of Cincinnati College of Medicine and completed his general surgery residency at Indiana University School of Medicine. Hari Kumar joined Community Heart and Vascular in October 2014. Having received his medical degree from Finch University of Health Sciences/The Chicago Medical School, he did his general surgery residency and his fellowship in thoracic and cardiovascular surgery at Loyola University- Foster McGraw Hospital, Maywood, Illinois. Most recently, he was in private practice in Muncie. Koelsch is board certified by the American Board of Thoracic Surgery. Koelsch, M.D., joined the Community Howard Regional Health medical staff as a cardiothoracic surgeon in 2013. He was a fellow at Indiana University School of Medicine. Klein received his medical degree from Hahnemann Medical College, Philadelphia, and did his internship and residency at University of North Carolina, Chapel Hill. Board certified in cardiovascular electrophysiology, cardiovascular disease and internal medicine, Dr. Klein has practiced in Indianapolis since 1986. Lawrence Klein, MD, joined the Community Howard Regional Health medical staff as a cardiologist in 2013. Hansen is board certified in vascular surgery. ![]() He completed his residency and a fellowship at the Hennepin County Medical Center in downtown Minneapolis.ĭr. Hansen received his medical degree from University of Minnesota Medical School. ![]() Guttikonda is board certified in vascular surgery. He completed his residency and a fellowship at the Ohio State University Medical Center.ĭr. Guttikonda received his medical degree from Northeastern Ohio University College of Medicine. Need heart care? Call 76 to schedule an appointment with a Community Howard heart and vascular specialist. ![]()
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![]() ![]() That’s just part of the service we provide in an effort to maintain our customers’ vehicles in a safe operating condition so that they and their loved ones will have dependable, worry-free driving,” explains Leon. “That way, we can alert customers of any condition that may need attention before it turns into a costly problem. The shop offers services on all makes and models, and each comes with a satisfaction guarantee and a three-year/36,000-mile warranty.Įvery time a customer brings their vehicle in for service, Integrity Auto Care techs perform a thorough courtesy inspection. Leon received an all-expenses-paid trip to Las Vegas to attend the AAPEX Show, as well as to participate in the WIX Filters and Babcox Media Night of Excellence recognition dinner held on Monday evening of show week.įrom simple oil changes to complex engine replacements, Integrity Auto Care has the solution for any automotive maintenance and repair need. ![]() The award recognizes game changers in automotive service - those shops that are raising the bar in customer service excellence. So, it’s no wonder that Integrity Auto Care was the 2016 recipient of the WIX Filters’ Driving Performance Award, which was given to Leon for his work in truly revolutionizing his customers’ vehicle repair experiences from start to finish. By living up to its name on a daily basis, the team delivers their customers’ vehicles in a safe, properly maintained operating condition - and they take pride in being the best automotive shop around, he adds. “Our name says it all, as we provide honest, superior-quality repairs, plus convenience and value in a modern, upscale facility,” says owner Leon Anderson, who formerly ran car dealerships before starting his own business.Ĭustomers truly experience a difference when they come to Integrity Auto Care, a service and repair facility that Leon says customers can finally call home. We perform all areas of maintenance and repairs.A general repair shop with eight bays, Integrity Auto Care in South Beloit, IL, is committed to fulfilling what its name implies. We are trained and equipped to work on all makes and models of domestic, Asian, and European vehicles. Integrity now has 13 full-time employees, we have serviced more than 47,000 vehicles, and our 6 ASE certified technicians have an average of 24 years’ experience. After just six weeks, they hired another technician, Marvin Gohl, who is our shop foreman to this day. Integrity Automotive opened in Issaquah in 1998 with two employees, Nate and his wife Susan. Nate developed his dream of opening a different type of business, one that values customer relationships and thoroughly understands what matters to you-reliability, safety, peace of mind, trustworthiness, and convenience. Founder Nate Bean earned a degree in Automotive Technology at Lake Washington Vocational Technical College. Integrity Automotive began with a simple belief-our belief that there is a better way to run an automotive shop. We are so confident in the quality of the parts we use and the skills of our career technicians that we stand behind our repairs forever, as long as you own your vehicle. We recognize your need for exceptional customer service, and we back up our commitment with the best warranties in the industry. We are committed to providing you with the highest quality professional repairs and service at a fair price. Our mission at Integrity Automotive is to make getting your vehicle serviced a more pleasant and less confusing experience. ![]() ![]() ![]() ![]() ![]() The studio is dedicated to creating quality user experiences for primarily mobile devices. House on Fire is an independent video game developer located in Copenhagen, Denmark, founded in 2011 and managed by Linda Randazzo and Uni Dahl. There are two episodes to it, released in 2012 and. The update is completely free to everyone who already owns the game, as a “thank you” for the incredible support – visit to learn more. The Silent Age is a point-and-click indie puzzle game created by a Danish game studio House On Fire. New voice-overs will also add a new dimension to the game’s immersion, “I’m sure you’ll find it a very different experience, so we’re looking forward to hearing your thoughts on the characters as they come to life,” adds the developer.įinally, after receiving many requests to localise the game, German, Russian, French, Italian, Spanish and Ukrainian fans of point-and-click adventures can now also enjoy The Silent Age in their own languages. Most popular community and official content for the past. A gift from the future allows you to manipulate time travel, an essential investigation tool you will need as you unravel the mysterious disappearance of every human being on the planet. “(Now) you can actually read Joe’s ’employee-of-the-month award’ in his ‘office’.” The Silent Age is a post-apocalyptic point & click puzzle adventure game. The Golden Age had begun around the late 1920’s, November 18th, 1928 to be exact. Better yet, a new age known as the Golden Age of animation will come forth and be better recognize as the more influential part of animation. But mobile devices have now become so powerful, with high-resolution retina displays, that it makes sense to bring these highly detailed visuals to mobile platforms as well,” says a spokesperson for House on Fire. Unfortunately, The Silent Age had to come to an end because of sound technology that started rising. The Silent Generation is generally defined as people born from 1928 to 1945. “When we released The Silent Age on PC, we ‘upped’ the graphics. The Silent Generation is the demographic cohort following the Greatest Generation and preceding the Baby Boomers. This free-to-play atmospheric point-and-click episodic adventure game with stylized visuals and an eerie soundtrack is split between two eras four decades apart and centers around an average guy named Joe who works in a government building as a janitor in present day 1972. You play as Joe, a humble cleaner with a red boiler suit and a moustache that'd make Tom Selleck jealous. And then there's a post-apocalyptic wasteland some four decades later, in 2012. Danish developer House on Fire has released a major update to The Silent Age for iOS and Android devices, including full HD retina graphics, new voice-acting, localisation into seven languages and over 20 achievements to unlock. The Silent Age for iOS, Android, and Steam is a new time-travelling episodic adventure, split between two eras. ![]() ![]() ![]() Gives the corresponding tertiary alcohol.Įxamples that you will be taught in any organic chemistry reactivity course,īetween organic compounds can be explained by just using his principle of Giving an intermediate alkoxyde, which after treatment with a proton source (H +), Ketone releases this charge polarization on the electrophilic ketone (this is Nucleophilic addition of organometallic reagents to electrophilic ketones In this example, a negatively charged carbon atom of a Grignard reagent, such as PhMgBr (phenyl magnesium bromide), acts as a nucleophile. Typical nucleophiles for ketones are organic or organometallic reagents with high electron density. In this way, nucleophiles can react with electrophiles. How Does Charge Distribution Result on Reactivity Trends? This charge distribution, makes the carbon atom of the carbonyl group a potential electrophile that can react with different nucleophiles. This is a combination of induction and resonance effects.īut the result is clear: a partial negative charge (□-) is generated at the oxygen atom, and a partial positive charge (□-) is generated at the carbonyl carbon atom. Oxygen is more electronegative than carbon, so it wants to hold the electrons of the covalent bond more than carbon. In this molecule, a electronegative atom (O) is covalently attached to a carbon. This is a great example of how electronics work. This second partner, which has low electron density and wants electrons, is called electrophile.Ī scheme of the most typical electrophile in organic chemistry: a carbonyl In very simple terms: we say that a molecule behaves as a nucleophile if it has a functional group that has a lot of electrons (high electron density), and wants to attack another functional group that lacks electrons. Generally, two organic molecules react because one part (or functional group) of one of the molecules has with high electron density ( nucleophile) and another part of another molecule, has a low electron density ( electrophile). If you have studied anything about reactivity of organic molecules, you know that the movement of electrons rules everything. Basic Organic Chemistry: What are Electronic Effects? So, we will try to cover that gap on this article. I would say that most textbooks are missing a specific general overview about this (although you can argue that this is the entirety of basic organic chemistry itself). We will show different examples on how these two are used to rationalize chemistry, both independently or in combination. We will explain what this combination is about, going through the basics of what electronic and steric effects are. This combination is key for grasping the big picture of organic chemistry. However, we like to think about a combination of steric and electronic effects as a simplified version of this concept. Stereoelectronics is not a concept that, by itself, is usually taught in introductory courses (if you check the Wikipedia page on it, for example, it shows a significantly advanced discussion). This simple but important concepts are the basis of most rationalizations or models in organic chemistry.Įlectronic and steric effects are the basis of most organic chemistry models. More accesible electriphilic centers will be more reactive, due to steric effects. In very simple terms, nucleophiles attack electrophilic positions due to electronic effects. In a very simplefied fashion, you can argue that you can explain everything in organic chemistry by arguments of either “ electronic effects“, “ steric effects“, or a combination of the two. Keep reading! What Is the Most Important Concept to Grasp in Basic Organic Chemistry? However, there are key concepts, specifically the one(s) we will discuss here, that will help you see organic chemistry from a brighter side. You obviously also need a solid background on general chemistry.Īnd yeah, learning how to run a perfect TLC helps too! To do so, a good organic chemistry textbook and a nice molecular modeling kit are gonna be your best companions. In any case, you really need to be prepared. The learning process that your brain must follow for o-chem is very different. This makes complete sense, since organic chemistry is a very unique branch of science. You are not alone feeling like this subject is special. 15 Adding in Steric Effects to Basic Organic Chemistry What Are the Keys for Learning Organic Chemistry? ![]() ![]() ![]() If you declare a variable without a value, then it is considered to have an undefined value. We have taken cycle as an object, and it has three properties and three values for the same. Now lets see how to declare the objects, JavaScript objects are to be written in a curly bracket. Note: Arrays have to be written in square brackets. We have declared an array sharplesson with three array items. Now we will see, how to declare the arrays using var. Don’t worry we will show the use of it in our examples. Note: If your code requires a conditional testing, then you can use Boolean. Boolean – ExampleĪs we know Boolean has only two values: True or False Note: you can declare any number (decimal or non-decimal) without any double or single quotes. We can use the same var to declare the number as well: Note: You can declare string either in a double quote or in a single quote. Unlike other languages, JavaScript has ‘var’ to hold any value, for example, if you want ‘var’ to declare the string, then you can do like: ![]() Because practical things are easy to understand: String – Example ![]() Now we will try to understand the data types with the use of the examples.
![]() ![]() A base class has, therefore, many forms: the base class itself, and any of its subclasses. In addition to allowing you to use dynamic cast, it also allows the proper destructors to be called when a base class pointer is deleted. Polymorphism, which etymologically means 'many forms,' is the ability to treat an object of any subclass of a base class as if it were an object of the base class. The simplest case, and probably worthwhile if you're passing pointers around like this, is to consider making the base class's destructor virtual. However, if the type in question does not have any virtual methods, then it cannot be used. ![]() It requires that the class in question have at least 1 virtual method, which allows the compiler (if it supports RTTI) to perform this additional check. A polymorphic variable is a variable that can hold values of different types. But the check is only at compile time, and the compiler assumes you know what you are doing.ĭynamic_cast can only be used in the case of a pointer or reference cast, and in addition to the compile time check, it does an additional run time check that the cast is legal. A simple and easy program to understand the concept of runtime polymorphism, compile time polymorpism,overloading, overridding, downcasting, upcasting and Interface. Self and Super Downcasting (Reverse Polymorphism) Pure Polymorphism. C++ allows that a derived class pointer (or reference) to be treated as a base class pointer. The reason why: static_cast basically has the compiler perform a check at compile time "Could the input be cast to the output?" This is can be used for cases where you are casting up or down an inheritance hierarchy of pointers (or references). It can be achieved by using Polymorphism. static_cast is the cast you would use in this case, if you know that it is in fact an object of the target type. Im reading up a book on Java and currently on the Polymorphism topic as well as how to downcast a reference variable. Downcasting and run-time type identification. Syntax errors non-withstanding, you cannot dynamic_cast a non-polymorphic type. ![]() ![]() I want people to see another great fight. It’s been a dream and vision of mine to fight representing the WBC. ![]() “I want to offer my thanks and appreciation to the WBC and Golden Boy for the opportunity to fight the world title. I am fully confident that my skills will help me come out on top, and I will prove to everybody why I am the WBC reigning flyweight champion and the best in the division.” ![]() I´m proud to bring my title and defend it against a fighter with Esparza’s experience. “It will be my first fight in the United States, so this is a great chance to show everybody what I am capable of by fighting on a massive stage on a Golden Boy event live on DAZN. “I am so excited for this world title defense against Marlen Esparza,” said Ibeth Zamora. I’m not coming to lay down.”Īdditionally, Ibeth “La Roca” Zamora (32-6, 12 KOs) of San Cristobal Huichochitlan, Toluca, Mexico will defend her WBC flyweight world championship against Olympic bronze medalist Marlen Esparza (9-1, 1 KO) of Houston, Texas in a 10-round fight. People don’t know I had a lot of injuries in my career but no excuses. ”Training camp is going great,” said Nagy Aguilera. Aguilera is coming off a unanimous decision win against Terrel Jamal Woods in November 2020. The native of Newburgh, New Jersey has faced the likes of Antonio “Magic Man” Tarver, Chris “The Nightmare” Arreola and Dominic “Trouble” Breazeale. He is dedicated and skilled-the total package.”Īguilera is a 34-year-old boxer who made his professional debut in August 2007. “We are excited to show America the biggest threat to the heavyweight division,” said Camille Estephan, President of Eye of the Tiger Management. “The ‘Lion’ is coming to destroy everyone in the heavyweight division,” said Arslanbek Makhmudov. Makhmudov, who now calls Montreal, Quebec, Canada his home, has no doubts about what he wants do with his professional career. Before turning professional in 2017, he was an international amateur standout, where he competed in various tournaments, including the World Series of Boxing.Īs a professional, the 31-year-old contender has ended all of his fights by knockout, including a first-round win against former world champion Samuel “The Nigerian Nightmare” Peter to win the NABF Heavyweight Title. Standing at six feet five and a half inches tall, Makhmudov is a Russian monster who weighs as much as 260 pounds when stepping into the ring. “We are very proud to be working with our partners at Eye of The Tiger Management as we enter a new phase in Makhmudov’s career, one which will see him become a world champion and dominate the biggest names of this weight class.” “Arslanbek Makhmudov is perhaps the most dangerous fighter in the heavyweight division,” said Oscar De La Hoya, Chairman and CEO of Golden Boy. ![]() For detailed COVID-19 event safety fan protocols, click here or visit. The event will be held under strict COVID-19 fan safety protocols and with a reduced event capacity below 40%. The event will take place on Friday, April 23 at The University of Texas at El Paso’s Don Haskins Center and will be streamed live exclusively on DAZN worldwide, excluding Mexico, beginning at 6:00 p.m. The bout will be presented in association with Eye of the Tiger Management. Heavyweight monster Arslanbek “Lion” Makhmudov (11-0, 11 KOs) will make his highly anticipated United States debut as he defends his NABF title against Nagy “Dominican Dynamite” Aguilera(21-10, 14 KOs) in the 10-round co-main event of Munguia vs. ![]() ![]() ![]() This app has cheats for PS3/PS4 and Xbox 360/Xbox One. There are actually two different types of GTA 5 Cheats PS4 and Xbox One. Cheat Codes For Gta 5 Ps3 Money Online & Cheat Codes For Gta 5 Xbox 360 Unlimited Money. com has more content than anyone else to help you win all PlayStation 4 (PS4) games! 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Channel owners convicted of egregious crime may be barred if the content is closely related to the crime, according to the guidelines, making Kelly liable on the basis that he used his fame and power to establish his racketeering enterprise. ![]() The accounts were terminated “in accordance with creator responsibility guidelines,” the spokesperson said. Kelly Vevo, a spokesperson for the platform has confirmed. ![]() ![]() ![]() Cons It’s not the most original game out there. ![]() Tons of cool power-ups to get and power-downs to avoid. Pros Simple, addictive, fun and easy to learn. Download Free Games is a small business owned and operated by iWin Inc. DFG is constantly expanding, striving to bring its audience the most entertaining game downloads found on the Internet. Whatever the case may be, DX-Ball is an amusing diversion that you can play for free on most any kind of computer these days. DX-Ball has a number of issues that can make it more frustrating than fun at times. 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It means a benign program is wrongfully flagged as malicious due to an overly broad detection signature or algorithm used in an antivirus program. We have scanned the file and URLs associated with this software program in more than 50 of the world’s leading antivirus services no possible threat has been detected.īased on our scan system, we have determined that these flags are possibly false positives. This comprehensive process allows us to set a status for any downloadable file as follows. Our team performs checks each time a new file is uploaded and periodically reviews files to confirm or update their status. – Конечно.ĭX-Ball (Windows) Game Download – Brick Breaking has remained the most popular game type! DX Ball continues this trend! ![]() |
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